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11. Prince Charles and Princess Diana
A fairytale wedding ended with a nightmarish divorce for this next famous celebrity couple. In 1981, Prince Charles and Princess Diana became the talk of the world when they announced their engagement. Prince Charles, the eldest son of Queen Elizabeth II, briefly courted and then wed Princess Diana at the majestic St. Paul’s Cathedral. Beloved by the public, the two seemed picturesque with their two sons, princes William and Harry. However, the two sought divorce when their incompatibility and extramarital affairs became public. The couple ultimately separated in 1992. Once the media became vicious about their break, Prince Charles and Princess Diana finalized their divorce in 1996.